1 00:00:15,669 --> 00:00:12,629 all right it's uh it's a it's a real 2 00:00:16,550 --> 00:00:15,679 pleasure to introduce uh germano de 3 00:00:18,390 --> 00:00:16,560 brama 4 00:00:19,910 --> 00:00:18,400 um someone's whose research i've been 5 00:00:22,310 --> 00:00:19,920 following for about 10 years but i've 6 00:00:24,710 --> 00:00:22,320 never actually met so 7 00:00:26,870 --> 00:00:24,720 um germano is a physicist and worked as 8 00:00:29,269 --> 00:00:26,880 a researcher 9 00:00:31,269 --> 00:00:29,279 in various institutes and companies in 10 00:00:33,510 --> 00:00:31,279 rome between 1998 11 00:00:35,750 --> 00:00:33,520 and 2014 on near-earth asteroid 12 00:00:37,990 --> 00:00:35,760 population modeling and deflection 13 00:00:40,069 --> 00:00:38,000 his research activities and interests 14 00:00:41,750 --> 00:00:40,079 also include special relativity 15 00:00:44,549 --> 00:00:41,760 classical electrodynamics and the 16 00:00:45,990 --> 00:00:44,559 history of the philosophy of physics 17 00:00:47,510 --> 00:00:46,000 he currently works for the italian 18 00:00:49,990 --> 00:00:47,520 ministry of education as a physics 19 00:00:53,350 --> 00:00:50,000 teacher he is the author of the books 20 00:00:56,950 --> 00:00:53,360 the impact clan in 2015 and probing the 21 00:00:59,029 --> 00:00:56,960 limits in 2017. 22 00:01:00,630 --> 00:00:59,039 uh germano 23 00:01:01,670 --> 00:01:00,640 please um 24 00:01:04,400 --> 00:01:01,680 thank you 25 00:01:08,070 --> 00:01:06,070 it's a real pleasure for me to be here 26 00:01:11,429 --> 00:01:08,080 with you 27 00:01:14,469 --> 00:01:11,439 let me share my my presentation hope you 28 00:01:23,830 --> 00:01:14,479 care you can 29 00:01:23,840 --> 00:01:28,789 oh sorry 30 00:01:28,799 --> 00:01:36,630 sorry 31 00:01:41,350 --> 00:01:39,510 can you see my presentation yes 32 00:01:43,429 --> 00:01:41,360 okay the presentation looks good we can 33 00:01:45,590 --> 00:01:43,439 hear you just fine 34 00:01:48,230 --> 00:01:45,600 well what i'm going to to present today 35 00:01:49,670 --> 00:01:48,240 is the results of my contribution to the 36 00:01:51,590 --> 00:01:49,680 to the challenge 37 00:01:54,789 --> 00:01:51,600 to the second law of thermodynamics that 38 00:01:55,510 --> 00:01:54,799 i they may i did more than 10 years ago 39 00:01:57,190 --> 00:01:55,520 and 40 00:02:00,870 --> 00:01:57,200 for which i i want to acknowledge the 41 00:02:03,830 --> 00:02:00,880 kind moral support from daniel sheehan 42 00:02:05,749 --> 00:02:03,840 since then i never come back to this 43 00:02:08,389 --> 00:02:05,759 research so what you are we will say 44 00:02:09,830 --> 00:02:08,399 today is more or less a still picture of 45 00:02:11,190 --> 00:02:09,840 10 years ago 46 00:02:13,589 --> 00:02:11,200 but i believe 47 00:02:15,350 --> 00:02:13,599 the results are still interesting and 48 00:02:18,630 --> 00:02:15,360 worth telling 49 00:02:21,270 --> 00:02:18,640 well what's this all about 50 00:02:22,949 --> 00:02:21,280 well i have studied analytically and 51 00:02:25,750 --> 00:02:22,959 numerically 52 00:02:28,790 --> 00:02:25,760 this simple and well-known idea 53 00:02:30,869 --> 00:02:28,800 exploiting the photoelectric effect 54 00:02:34,309 --> 00:02:30,879 of the black body radiation on materials 55 00:02:36,309 --> 00:02:34,319 with different work functions 56 00:02:37,270 --> 00:02:36,319 let me remind briefly what our function 57 00:02:42,229 --> 00:02:37,280 is 58 00:02:44,949 --> 00:02:42,239 energy required to extract an electron 59 00:02:46,630 --> 00:02:44,959 from the bulk of a material to a to its 60 00:02:50,309 --> 00:02:46,640 surface 61 00:02:52,869 --> 00:02:50,319 what you see on the left is a sketch 62 00:02:56,070 --> 00:02:52,879 of a capacitor which have dubbed the 63 00:02:57,589 --> 00:02:56,080 thermal charger capacitor tcc 64 00:02:58,949 --> 00:02:57,599 where two plates 65 00:03:01,910 --> 00:02:58,959 a and b 66 00:03:03,350 --> 00:03:01,920 are housed inside a vacuum vessel 67 00:03:11,110 --> 00:03:03,360 and 68 00:03:13,110 --> 00:03:11,120 are made of the same metal with the 69 00:03:15,350 --> 00:03:13,120 work function feature 70 00:03:18,070 --> 00:03:15,360 uh plate b is coated with a 71 00:03:20,390 --> 00:03:18,080 semiconductor with a mature with a much 72 00:03:22,710 --> 00:03:20,400 lower work function v1 73 00:03:25,350 --> 00:03:22,720 and the whole device is 74 00:03:27,750 --> 00:03:25,360 is at uniform temperature 75 00:03:29,830 --> 00:03:27,760 but plates amb 76 00:03:32,710 --> 00:03:29,840 receive photons from the black body 77 00:03:34,070 --> 00:03:32,720 radiation but being feature the work 78 00:03:37,509 --> 00:03:34,080 function of the 79 00:03:43,830 --> 00:03:39,990 of a or the electrode a 80 00:03:46,390 --> 00:03:43,840 greater than v1 the electrons extracted 81 00:03:49,350 --> 00:03:46,400 by the photoelectric effect of from from 82 00:03:52,309 --> 00:03:49,360 the coating of b to plate a 83 00:03:54,470 --> 00:03:52,319 are more numerous and with a higher 84 00:03:57,429 --> 00:03:54,480 kinetic energy than those extracted from 85 00:03:58,710 --> 00:03:57,439 plate a to plate b 86 00:04:00,470 --> 00:03:58,720 at least at the 87 00:04:01,750 --> 00:04:00,480 in the yearly phases of the of the 88 00:04:02,869 --> 00:04:01,760 process 89 00:04:04,390 --> 00:04:02,879 on the right 90 00:04:07,670 --> 00:04:04,400 there is a sketch 91 00:04:09,030 --> 00:04:07,680 of the black body radiation distribution 92 00:04:11,509 --> 00:04:09,040 this gives 93 00:04:13,589 --> 00:04:11,519 the split the spectral radiance versus 94 00:04:16,949 --> 00:04:13,599 the frequency 95 00:04:20,550 --> 00:04:16,959 well it roughly tells us the number of 96 00:04:23,110 --> 00:04:20,560 photons with a given energy each node 97 00:04:25,110 --> 00:04:23,120 in term in the thermal radiation at a 98 00:04:27,990 --> 00:04:25,120 specific temperature and 99 00:04:29,590 --> 00:04:28,000 it is easy to to see why more electrons 100 00:04:32,310 --> 00:04:29,600 are extracted from 101 00:04:34,150 --> 00:04:32,320 me to a within and with an higher 102 00:04:36,870 --> 00:04:34,160 kinetic energy 103 00:04:38,230 --> 00:04:36,880 um all that means that a net flux of 104 00:04:40,550 --> 00:04:38,240 electrons 105 00:04:42,550 --> 00:04:40,560 should flow from 106 00:04:44,390 --> 00:04:42,560 plate b to plate a 107 00:04:51,510 --> 00:04:44,400 and therefore there should be an 108 00:04:57,189 --> 00:04:52,790 okay so 109 00:05:02,150 --> 00:04:59,430 well in the case of an open circuit tcc 110 00:05:04,469 --> 00:05:02,160 at equilibrium like in in the image on 111 00:05:06,550 --> 00:05:04,479 the left we expect that 112 00:05:09,510 --> 00:05:06,560 after a suitable interval time an 113 00:05:11,830 --> 00:05:09,520 equilibrium potential difference delta v 114 00:05:13,029 --> 00:05:11,840 is established across the 115 00:05:15,670 --> 00:05:13,039 the plates 116 00:05:18,310 --> 00:05:15,680 and at equilibrium delta v 117 00:05:22,070 --> 00:05:18,320 is necessarily equal to v2 118 00:05:24,950 --> 00:05:22,080 minus v1 divided by the electron charge 119 00:05:27,909 --> 00:05:24,960 because only only with that value 120 00:05:29,029 --> 00:05:27,919 the energy needed by an electron to get 121 00:05:32,230 --> 00:05:29,039 extracted 122 00:05:33,670 --> 00:05:32,240 from the coating of b of plate b 123 00:05:36,790 --> 00:05:33,680 and the rich plate 124 00:05:39,189 --> 00:05:36,800 becomes equal to to the energy needed by 125 00:05:41,909 --> 00:05:39,199 an electron to get extracted from plate 126 00:05:43,590 --> 00:05:41,919 a and reach plate b 127 00:05:45,670 --> 00:05:43,600 all in this case 128 00:05:47,189 --> 00:05:45,680 there will be no more imbalance in the 129 00:05:51,110 --> 00:05:47,199 two fluxes of 130 00:05:56,629 --> 00:05:54,310 well in the case of a short circuit dcc 131 00:05:58,710 --> 00:05:56,639 uh on the right 132 00:06:02,629 --> 00:05:58,720 uh a current i should flow across the 133 00:06:05,029 --> 00:06:02,639 circuit um and and if the resistance of 134 00:06:08,070 --> 00:06:05,039 the circuit external to the 135 00:06:08,950 --> 00:06:08,080 the tcc is negligible and that current 136 00:06:10,950 --> 00:06:08,960 should be 137 00:06:16,629 --> 00:06:10,960 equal to the thermionic 138 00:06:21,909 --> 00:06:19,510 now before getting to 139 00:06:25,670 --> 00:06:21,919 mata the mathematical numerical 140 00:06:28,150 --> 00:06:25,680 simulation of a tcc uh let me dwell on 141 00:06:29,830 --> 00:06:28,160 two objections that could be 142 00:06:32,469 --> 00:06:29,840 advanced 143 00:06:33,430 --> 00:06:32,479 i must warn you that this part 144 00:06:35,430 --> 00:06:33,440 the next 145 00:06:38,790 --> 00:06:35,440 two slides um 146 00:06:41,590 --> 00:06:38,800 are a bit involved but i try to keep 147 00:06:43,270 --> 00:06:41,600 it as simple and short as possible 148 00:06:44,390 --> 00:06:43,280 it is important to reply to these 149 00:06:46,390 --> 00:06:44,400 objections 150 00:06:49,909 --> 00:06:46,400 because if they were correct 151 00:06:52,469 --> 00:06:49,919 the tcc will not work uh as expected 152 00:06:55,510 --> 00:06:52,479 and uh to better introduce them these 153 00:06:57,909 --> 00:06:55,520 two objections uh let me switch to 154 00:07:00,950 --> 00:06:57,919 a topological ana analog 155 00:07:03,749 --> 00:07:00,960 of the short circuit dcc on the left 156 00:07:06,390 --> 00:07:03,759 and it is this uh horseshoe shaped thing 157 00:07:07,909 --> 00:07:06,400 on right on the right 158 00:07:09,110 --> 00:07:07,919 the right half of 159 00:07:11,990 --> 00:07:09,120 the horseshoe 160 00:07:15,110 --> 00:07:12,000 represents a plate a 161 00:07:17,029 --> 00:07:15,120 part of plate b and the connecting wire 162 00:07:19,430 --> 00:07:17,039 with things 163 00:07:21,110 --> 00:07:19,440 and all this stuff as work function 164 00:07:22,629 --> 00:07:21,120 equal to feature 165 00:07:25,029 --> 00:07:22,639 the left 166 00:07:25,990 --> 00:07:25,039 alpha is the coating of plate b 167 00:07:29,670 --> 00:07:26,000 and 168 00:07:32,309 --> 00:07:29,680 it has a work function equal to v1 169 00:07:34,070 --> 00:07:32,319 in both images 170 00:07:36,230 --> 00:07:34,080 j2 171 00:07:38,950 --> 00:07:36,240 indicates the button gap between the 172 00:07:43,749 --> 00:07:41,510 well it is known that when two materials 173 00:07:46,150 --> 00:07:43,759 with different work functions in 174 00:07:48,710 --> 00:07:46,160 particular a metal and an n-type 175 00:07:50,469 --> 00:07:48,720 semiconductor like in our case 176 00:07:54,070 --> 00:07:50,479 are physically joined 177 00:07:57,189 --> 00:07:54,080 a potential difference delta v 178 00:07:59,510 --> 00:07:57,199 builds up across the content junction j1 179 00:08:01,270 --> 00:07:59,520 this potential is called the 180 00:08:04,469 --> 00:08:01,280 content potential 181 00:08:07,029 --> 00:08:04,479 and it is generated by 182 00:08:09,350 --> 00:08:07,039 the electrons that are pushed 183 00:08:10,869 --> 00:08:09,360 from v2 materials 184 00:08:12,550 --> 00:08:10,879 the yellowish one 185 00:08:15,510 --> 00:08:12,560 to the 186 00:08:19,510 --> 00:08:15,520 2 feet 2 materials across the g1 187 00:08:22,150 --> 00:08:19,520 by thermally driven diffusion forces 188 00:08:24,230 --> 00:08:22,160 a higher amount of electrons move from 189 00:08:25,350 --> 00:08:24,240 left to right rather than the other way 190 00:08:26,469 --> 00:08:25,360 around 191 00:08:28,629 --> 00:08:26,479 simply because 192 00:08:31,909 --> 00:08:28,639 it's easier to pull electrons out of a 193 00:08:35,029 --> 00:08:31,919 lower work function material 194 00:08:37,509 --> 00:08:35,039 the diffusion process lasts until 195 00:08:38,630 --> 00:08:37,519 a dynamical equilibrium is reached 196 00:08:41,110 --> 00:08:38,640 between 197 00:08:42,070 --> 00:08:41,120 the diffusion forces that push electrons 198 00:08:45,509 --> 00:08:42,080 to 199 00:08:47,269 --> 00:08:45,519 and the electric force do they built in 200 00:08:50,630 --> 00:08:47,279 electric fields 201 00:08:56,070 --> 00:08:52,949 also in this case the the the potent the 202 00:08:58,710 --> 00:08:56,080 contact potential delta v is equal to v2 203 00:08:59,910 --> 00:08:58,720 minus minus v1 divided by the electron 204 00:09:02,550 --> 00:08:59,920 charge 205 00:09:04,790 --> 00:09:02,560 and the reason is the reason is the same 206 00:09:06,550 --> 00:09:04,800 as in the previous slide for the final 207 00:09:09,590 --> 00:09:06,560 equilibrium 208 00:09:10,310 --> 00:09:09,600 of the thermionic charging process 209 00:09:12,230 --> 00:09:10,320 and 210 00:09:14,630 --> 00:09:12,240 the built-in electric field 211 00:09:16,949 --> 00:09:14,640 across j1 is roughly equal to the 212 00:09:19,670 --> 00:09:16,959 contact potential divided by the width 213 00:09:20,949 --> 00:09:19,680 of the depletion depletion region 214 00:09:23,269 --> 00:09:20,959 xd 215 00:09:25,030 --> 00:09:23,279 and naming namely the 216 00:09:28,389 --> 00:09:25,040 the thin layer across 217 00:09:30,949 --> 00:09:28,399 j1 where the diffusion of electrons 218 00:09:31,829 --> 00:09:30,959 has taken place 219 00:09:33,750 --> 00:09:31,839 well 220 00:09:36,630 --> 00:09:33,760 it is also 221 00:09:39,829 --> 00:09:36,640 a while a widely held belief that as 222 00:09:43,110 --> 00:09:39,839 soon as one joins 223 00:09:45,269 --> 00:09:43,120 the two halves at g1 224 00:09:49,430 --> 00:09:45,279 a potential difference equal and 225 00:09:52,790 --> 00:09:49,440 opposite to the contact potential 226 00:09:56,150 --> 00:09:52,800 here g1 should instantaneously beats up 227 00:09:58,389 --> 00:09:56,160 also across the gap j2 228 00:10:00,550 --> 00:09:58,399 notice that this potential the delta v 229 00:10:02,870 --> 00:10:00,560 across g2 across the gap 230 00:10:05,910 --> 00:10:02,880 is not that deriving from the thermionic 231 00:10:10,150 --> 00:10:07,829 it is intended to 232 00:10:11,350 --> 00:10:10,160 to be instantaneously generated by the 233 00:10:12,790 --> 00:10:11,360 movement 234 00:10:14,310 --> 00:10:12,800 of electrons in the bulk of the 235 00:10:17,590 --> 00:10:14,320 horseshoe 236 00:10:18,949 --> 00:10:17,600 and just after the physical contact 237 00:10:20,069 --> 00:10:18,959 of the materials 238 00:10:21,829 --> 00:10:20,079 materials 239 00:10:24,069 --> 00:10:21,839 at j1 240 00:10:27,269 --> 00:10:24,079 well people expect the potential 241 00:10:30,150 --> 00:10:27,279 difference across j2 across the gap 242 00:10:32,150 --> 00:10:30,160 because of an allegedly straightforward 243 00:10:35,670 --> 00:10:32,160 application of the kishuf 244 00:10:40,949 --> 00:10:38,310 well what is the problem with that 245 00:10:43,750 --> 00:10:40,959 well if the potential difference 246 00:10:45,829 --> 00:10:43,760 were really there across the gap 247 00:10:47,990 --> 00:10:45,839 then the thermionic charging process 248 00:10:50,630 --> 00:10:48,000 across g2 249 00:10:52,470 --> 00:10:50,640 could not even start 250 00:10:54,230 --> 00:10:52,480 since the delta v 251 00:10:57,350 --> 00:10:54,240 across j2 252 00:10:59,670 --> 00:10:57,360 is equal to v2 minus v1 okay 253 00:11:01,910 --> 00:10:59,680 divided by the electron charge 254 00:11:04,230 --> 00:11:01,920 and no net electron flux 255 00:11:05,910 --> 00:11:04,240 from plate b to plate a could be 256 00:11:09,509 --> 00:11:05,920 possible 257 00:11:14,710 --> 00:11:12,949 as i ever as i have described before 258 00:11:16,310 --> 00:11:14,720 the energy required 259 00:11:18,230 --> 00:11:16,320 uh for an electro to get a structure 260 00:11:20,550 --> 00:11:18,240 from the plate uh 261 00:11:21,910 --> 00:11:20,560 from one plate to reach the other 262 00:11:25,110 --> 00:11:21,920 will be the same 263 00:11:27,350 --> 00:11:25,120 in this case and incidentally equal to 264 00:11:29,750 --> 00:11:27,360 v2 265 00:11:31,110 --> 00:11:29,760 and therefore there will be no 266 00:11:34,550 --> 00:11:31,120 displacement 267 00:11:36,389 --> 00:11:34,560 of electrons across j across the gap j2 268 00:11:38,230 --> 00:11:36,399 and therefore there will be no current 269 00:11:42,550 --> 00:11:38,240 in the short circuit pcc 270 00:11:49,269 --> 00:11:45,430 moreover and this is the objection to 271 00:11:52,310 --> 00:11:49,279 uh even if a net flux of electrons 272 00:11:54,629 --> 00:11:52,320 were possible across the gap 273 00:11:56,710 --> 00:11:54,639 still the current will not flow across 274 00:12:01,030 --> 00:11:56,720 the the wall circuit 275 00:12:03,590 --> 00:12:01,040 in fact j1 is a metal and type 276 00:12:05,030 --> 00:12:03,600 semiconductor junction also known as 277 00:12:07,269 --> 00:12:05,040 shock junction 278 00:12:10,230 --> 00:12:07,279 and it is known to have a rectifying 279 00:12:13,590 --> 00:12:10,240 property rectifying properties okay 280 00:12:16,629 --> 00:12:13,600 under biasing electrons easy flow from 281 00:12:19,030 --> 00:12:16,639 the semiconductor to the metal 282 00:12:21,110 --> 00:12:19,040 from left to right across g1 but not 283 00:12:23,110 --> 00:12:21,120 that easily from the other way around 284 00:12:25,990 --> 00:12:23,120 from right to left across 285 00:12:31,509 --> 00:12:29,110 okay let me give a 286 00:12:34,069 --> 00:12:31,519 short reply to objection one 287 00:12:36,550 --> 00:12:34,079 well i my stand is that there is no 288 00:12:40,150 --> 00:12:36,560 instantaneous potential difference 289 00:12:42,629 --> 00:12:40,160 across the two across the gap j2 caused 290 00:12:44,230 --> 00:12:42,639 by the physical joining of the materials 291 00:12:46,470 --> 00:12:44,240 of the two materials 292 00:12:48,389 --> 00:12:46,480 at j1 293 00:12:50,389 --> 00:12:48,399 to prove that i applied the basic 294 00:12:52,870 --> 00:12:50,399 definition of 295 00:12:56,069 --> 00:12:52,880 potential difference the potential 296 00:12:58,389 --> 00:12:56,079 difference between two points a and b 297 00:12:59,670 --> 00:12:58,399 is defined as minus 298 00:13:02,069 --> 00:12:59,680 okay minus 299 00:13:02,790 --> 00:13:02,079 the work done by the forces acting upon 300 00:13:05,430 --> 00:13:02,800 the 301 00:13:08,150 --> 00:13:05,440 upon an electron that moves 302 00:13:10,629 --> 00:13:08,160 all along the path gamma 303 00:13:12,310 --> 00:13:10,639 joining a and b divided by the electron 304 00:13:14,790 --> 00:13:12,320 charge 305 00:13:16,470 --> 00:13:14,800 um i do this calculation 306 00:13:18,150 --> 00:13:16,480 along the blue line 307 00:13:22,389 --> 00:13:18,160 on the right 308 00:13:23,910 --> 00:13:22,399 in the back of the shoe across g1 309 00:13:25,509 --> 00:13:23,920 here 310 00:13:27,829 --> 00:13:25,519 effient 311 00:13:29,829 --> 00:13:27,839 stands for all forcing all the forces 312 00:13:32,230 --> 00:13:29,839 acting upon 313 00:13:34,389 --> 00:13:32,240 the elect the test electron 314 00:13:36,310 --> 00:13:34,399 when it moves across 315 00:13:39,269 --> 00:13:36,320 the path gamma 316 00:13:42,230 --> 00:13:39,279 uh from equilibrium consideration uh it 317 00:13:44,470 --> 00:13:42,240 is clear that f inter the the sum of the 318 00:13:47,269 --> 00:13:44,480 two forces or the all the forces acting 319 00:13:49,110 --> 00:13:47,279 upon the detected electron 320 00:13:51,750 --> 00:13:49,120 can be different from zero only across 321 00:13:52,550 --> 00:13:51,760 the the junction j1 322 00:13:56,069 --> 00:13:52,560 when 323 00:13:59,189 --> 00:13:56,079 the text electron crosses j1 324 00:14:01,269 --> 00:13:59,199 it does feel only two kinds of forces 325 00:14:02,550 --> 00:14:01,279 the diffusion forces pushing to the 326 00:14:04,389 --> 00:14:02,560 right 327 00:14:06,470 --> 00:14:04,399 and the electric force 328 00:14:08,629 --> 00:14:06,480 due to the built-in electric field 329 00:14:09,750 --> 00:14:08,639 pushing to the left 330 00:14:12,230 --> 00:14:09,760 um 331 00:14:15,350 --> 00:14:12,240 by the way the test electron does feel 332 00:14:16,790 --> 00:14:15,360 the diffusion forces exactly like all 333 00:14:21,910 --> 00:14:16,800 the electrons 334 00:14:25,829 --> 00:14:23,269 okay since 335 00:14:27,670 --> 00:14:25,839 the the diffusion forces dynamically 336 00:14:29,750 --> 00:14:27,680 sustain the electric field 337 00:14:31,110 --> 00:14:29,760 at j1 338 00:14:33,590 --> 00:14:31,120 by the way 339 00:14:34,790 --> 00:14:33,600 if i switch it off the diffusion forces 340 00:14:36,629 --> 00:14:34,800 at j1 341 00:14:38,150 --> 00:14:36,639 the beating electric field will go to 342 00:14:39,670 --> 00:14:38,160 zero 343 00:14:41,350 --> 00:14:39,680 so since the diffusion force is 344 00:14:43,350 --> 00:14:41,360 dynamically sustained in the electric 345 00:14:45,910 --> 00:14:43,360 field the g1 these two forces the 346 00:14:49,750 --> 00:14:45,920 electric forces and the diffusion forces 347 00:14:52,389 --> 00:14:49,760 must be always be present across j1 348 00:14:54,870 --> 00:14:52,399 and but and also must be equal in 349 00:14:56,150 --> 00:14:54,880 opposite equilibrium 350 00:14:58,230 --> 00:14:56,160 therefore 351 00:14:59,430 --> 00:14:58,240 the total force is equal to zero on 352 00:15:01,829 --> 00:14:59,440 average 353 00:15:04,389 --> 00:15:01,839 and together with the delta v 354 00:15:07,910 --> 00:15:04,399 uh between any two points a and b in the 355 00:15:09,750 --> 00:15:07,920 back of the in this ocean shaped 356 00:15:13,430 --> 00:15:09,760 thing 357 00:15:15,670 --> 00:15:13,440 all that means that physically joining 358 00:15:18,069 --> 00:15:15,680 different materials at j1 359 00:15:19,910 --> 00:15:18,079 cannot instantaneously cause any 360 00:15:22,310 --> 00:15:19,920 potential drop 361 00:15:24,150 --> 00:15:22,320 across the gap 362 00:15:27,590 --> 00:15:24,160 that will kill the terminic process from 363 00:15:29,749 --> 00:15:28,389 okay 364 00:15:31,670 --> 00:15:29,759 let's face 365 00:15:34,310 --> 00:15:31,680 objection two 366 00:15:36,150 --> 00:15:34,320 we know that every shock junction is 367 00:15:39,189 --> 00:15:36,160 characterized by a reverse leakage 368 00:15:40,949 --> 00:15:39,199 current that overcome 369 00:15:41,910 --> 00:15:40,959 the rectifying barrier 370 00:15:43,269 --> 00:15:41,920 and 371 00:15:45,269 --> 00:15:43,279 that current 372 00:15:47,350 --> 00:15:45,279 may be high or low depending up upon 373 00:15:49,509 --> 00:15:47,360 several factors 374 00:15:50,710 --> 00:15:49,519 for instance according to the the 375 00:15:51,990 --> 00:15:50,720 literature 376 00:15:55,030 --> 00:15:52,000 it may range 377 00:15:58,389 --> 00:15:55,040 from 10 to the 8 to 10 to the minus 2 378 00:16:01,749 --> 00:15:58,399 amps per square centimeter 379 00:16:07,110 --> 00:16:04,550 obviously depends upon the earth's bias 380 00:16:08,389 --> 00:16:07,120 but this dependence is quite flat so to 381 00:16:10,470 --> 00:16:08,399 speak 382 00:16:13,269 --> 00:16:10,480 reverse current doesn't change too much 383 00:16:15,189 --> 00:16:13,279 with the with the reverse bias 384 00:16:18,550 --> 00:16:15,199 at least below the the 385 00:16:20,470 --> 00:16:18,560 breakdown voltage but in our device 386 00:16:22,470 --> 00:16:20,480 we are very far from the breakdown 387 00:16:24,389 --> 00:16:22,480 voltage 388 00:16:26,470 --> 00:16:24,399 the reverse leakage current also depends 389 00:16:27,500 --> 00:16:26,480 upon the material used in the junction 390 00:16:29,749 --> 00:16:27,510 preparation 391 00:16:31,910 --> 00:16:29,759 [Music] 392 00:16:34,389 --> 00:16:31,920 for instance annealing seems to increase 393 00:16:37,110 --> 00:16:34,399 the reverse leakage current 394 00:16:39,350 --> 00:16:37,120 and it also depends upon the temperature 395 00:16:41,910 --> 00:16:39,360 the idea is that the temperature the the 396 00:16:43,990 --> 00:16:41,920 greater is the reverse current 397 00:16:47,110 --> 00:16:44,000 and also depends upon the the width of 398 00:16:48,470 --> 00:16:47,120 the depletion region xd 399 00:16:50,790 --> 00:16:48,480 since the thinner is the region the 400 00:16:53,189 --> 00:16:50,800 greater is the reverse current due to 401 00:16:57,829 --> 00:16:53,199 the tunneling effect 402 00:16:59,990 --> 00:16:57,839 so we see that even under a small bias 403 00:17:02,470 --> 00:17:00,000 a non-zero current can cross the 404 00:17:06,870 --> 00:17:02,480 junction even in the wrong direction so 405 00:17:09,990 --> 00:17:08,390 okay 406 00:17:12,949 --> 00:17:10,000 we finally come to my numerical 407 00:17:15,750 --> 00:17:12,959 simulation and results 408 00:17:17,750 --> 00:17:15,760 i mathematically model it 409 00:17:19,350 --> 00:17:17,760 as fact that this is 410 00:17:21,669 --> 00:17:19,360 and 411 00:17:24,549 --> 00:17:21,679 for the work function coating 412 00:17:27,429 --> 00:17:24,559 i have chosen the silver caesium oxide 413 00:17:28,789 --> 00:17:27,439 photocatal it is a well-known photocatal 414 00:17:30,630 --> 00:17:28,799 material 415 00:17:33,830 --> 00:17:30,640 and it is known in the literature to 416 00:17:36,470 --> 00:17:33,840 have a work function of nearly 0.7 417 00:17:38,549 --> 00:17:36,480 electron volts or 0.8 electro volts 418 00:17:40,390 --> 00:17:38,559 the inner and the outer 419 00:17:42,230 --> 00:17:40,400 spheres are made of metal with a work 420 00:17:45,190 --> 00:17:42,240 function 421 00:17:48,710 --> 00:17:45,200 equal to 4 electron volts 422 00:17:49,669 --> 00:17:48,720 the model of the dcc is 40 centimeters 423 00:17:51,990 --> 00:17:49,679 wide 424 00:17:53,909 --> 00:17:52,000 and as you may see 425 00:17:54,789 --> 00:17:53,919 the ratio between the outer and the 426 00:17:59,029 --> 00:17:54,799 inner 427 00:18:00,789 --> 00:17:59,039 radius is taken to be equal to two 428 00:18:02,789 --> 00:18:00,799 because it can be proven 429 00:18:05,430 --> 00:18:02,799 that this choices 430 00:18:07,590 --> 00:18:05,440 maximizes the the charging speed for an 431 00:18:09,990 --> 00:18:07,600 open circuit dcc 432 00:18:12,549 --> 00:18:10,000 um but the the charging speed is not a 433 00:18:13,830 --> 00:18:12,559 crucial feature here 434 00:18:15,909 --> 00:18:13,840 it's important 435 00:18:19,350 --> 00:18:15,919 is the power output of a short circuit 436 00:18:21,430 --> 00:18:19,360 vcc uh we show you in a moment 437 00:18:23,350 --> 00:18:21,440 another important parameter is the of 438 00:18:25,110 --> 00:18:23,360 this for the simulation is 439 00:18:27,029 --> 00:18:25,120 is the quantum efficiency of the 440 00:18:29,590 --> 00:18:27,039 materials 441 00:18:31,510 --> 00:18:29,600 quantum efficiency is roughly the ratio 442 00:18:33,590 --> 00:18:31,520 between the the number of electrons 443 00:18:35,350 --> 00:18:33,600 extracted by the radiation 444 00:18:37,270 --> 00:18:35,360 and the number of photons impinging on 445 00:18:38,789 --> 00:18:37,280 the on the material on the surface of 446 00:18:41,750 --> 00:18:38,799 the blades 447 00:18:44,950 --> 00:18:41,760 and it is clearly um 448 00:18:49,110 --> 00:18:44,960 frequency dependent parameter and i have 449 00:18:51,990 --> 00:18:49,120 plugged in the equation only mean values 450 00:18:54,950 --> 00:18:52,000 over over frequency 451 00:18:58,390 --> 00:18:54,960 and i have used the quite conservative 452 00:19:00,470 --> 00:18:58,400 there is for heater one and eta two 453 00:19:03,190 --> 00:19:00,480 according to the literature a more 454 00:19:05,350 --> 00:19:03,200 realistic value for eta one for the the 455 00:19:07,430 --> 00:19:05,360 quantum efficiency of the 456 00:19:09,750 --> 00:19:07,440 silver system of side coating 457 00:19:10,870 --> 00:19:09,760 will be 10 to the minus three 458 00:19:13,909 --> 00:19:10,880 and 459 00:19:17,669 --> 00:19:13,919 eta 2 equal to 1 460 00:19:21,590 --> 00:19:17,679 is surely not realistic i i 461 00:19:25,750 --> 00:19:24,150 that does not exist any material with 462 00:19:31,590 --> 00:19:25,760 the work with the quantum mechanics 463 00:19:31,600 --> 00:19:35,909 well sorry 464 00:19:38,470 --> 00:19:37,110 um 465 00:19:39,909 --> 00:19:38,480 well 466 00:19:42,390 --> 00:19:39,919 my interest at the time of the 467 00:19:44,789 --> 00:19:42,400 simulation was to explore the the worst 468 00:19:46,549 --> 00:19:44,799 case scenario and and to see if a i 469 00:19:48,549 --> 00:19:46,559 could i could get something different 470 00:19:50,950 --> 00:19:48,559 from zero and 471 00:19:53,590 --> 00:19:50,960 it seems to be the case as we i showed 472 00:19:55,669 --> 00:19:53,600 you in a moment 473 00:19:58,230 --> 00:19:55,679 okay 474 00:20:00,789 --> 00:19:58,240 this graph shows the the charging 475 00:20:03,110 --> 00:20:00,799 profile of an open circuit dcc 476 00:20:05,510 --> 00:20:03,120 as you may see even with 477 00:20:08,230 --> 00:20:05,520 the previous very conservative value 478 00:20:10,149 --> 00:20:08,240 values for quantum efficiency 479 00:20:11,990 --> 00:20:10,159 it is expected to reach a voltage of 480 00:20:14,390 --> 00:20:12,000 nearly 0.3 481 00:20:16,710 --> 00:20:14,400 volts in less than 2 hours 482 00:20:18,870 --> 00:20:16,720 more or less 483 00:20:20,630 --> 00:20:18,880 with more realistic values for the 484 00:20:23,190 --> 00:20:20,640 quantum efficiencies 485 00:20:24,789 --> 00:20:23,200 the same voltage is probably rigid in a 486 00:20:27,110 --> 00:20:24,799 few minutes 487 00:20:29,750 --> 00:20:27,120 and here you may see uh 488 00:20:31,830 --> 00:20:29,760 for the sake of completeness 489 00:20:36,630 --> 00:20:31,840 the differential equation that governs 490 00:20:41,190 --> 00:20:38,470 okay now let's 491 00:20:43,270 --> 00:20:41,200 let's see the more interesting case of a 492 00:20:44,310 --> 00:20:43,280 short circuit tcc 493 00:20:47,110 --> 00:20:44,320 and 494 00:20:49,669 --> 00:20:47,120 the graph shows the power output 495 00:20:52,710 --> 00:20:49,679 per unit area of the inner sphere 496 00:20:55,510 --> 00:20:52,720 sphere versus the steady state 497 00:20:57,990 --> 00:20:55,520 voltage across the vcc and the resistor 498 00:21:03,830 --> 00:21:00,630 by tuning the value of the external 499 00:21:04,520 --> 00:21:03,840 resistance r we can maximize the power 500 00:21:06,630 --> 00:21:04,530 output 501 00:21:09,350 --> 00:21:06,640 [Music] 502 00:21:13,270 --> 00:21:09,360 the maximum is obtained 503 00:21:16,390 --> 00:21:15,510 volts across the resistance of the order 504 00:21:19,110 --> 00:21:16,400 of 505 00:21:21,590 --> 00:21:19,120 10 to the 10 ohms 506 00:21:24,710 --> 00:21:21,600 and the the value of the 507 00:21:27,750 --> 00:21:24,720 the power output of this model pcc is of 508 00:21:29,190 --> 00:21:27,760 the order of 10 to the minus for 14 509 00:21:31,990 --> 00:21:29,200 watts 510 00:21:33,830 --> 00:21:32,000 this way this value may appear and 511 00:21:36,310 --> 00:21:33,840 in fact in fact is 512 00:21:38,149 --> 00:21:36,320 a bit disappointing 513 00:21:39,830 --> 00:21:38,159 and 514 00:21:42,710 --> 00:21:39,840 the current design 515 00:21:45,190 --> 00:21:42,720 surely has no hope to have an immediate 516 00:21:47,110 --> 00:21:45,200 application to the real world 517 00:21:49,270 --> 00:21:47,120 however as i said before the main goal 518 00:21:51,350 --> 00:21:49,280 of this work was to prove the geology 519 00:21:52,710 --> 00:21:51,360 the theoretical validity of the basic 520 00:21:55,029 --> 00:21:52,720 idea 521 00:21:57,430 --> 00:21:55,039 uh you know i believe that 522 00:21:59,750 --> 00:21:57,440 if we can experimentally and 523 00:22:00,549 --> 00:21:59,760 unambiguously confirmed 524 00:22:03,830 --> 00:22:00,559 the 525 00:22:06,230 --> 00:22:03,840 functioning of this design 526 00:22:07,909 --> 00:22:06,240 we we would have an incentive to study 527 00:22:12,149 --> 00:22:07,919 and work on a more 528 00:22:15,909 --> 00:22:14,149 okay let me finish my 529 00:22:18,070 --> 00:22:15,919 my presentation 530 00:22:21,510 --> 00:22:18,080 with some basic and i'm i'm sure 531 00:22:23,110 --> 00:22:21,520 unsurprising prescription for a future 532 00:22:24,710 --> 00:22:23,120 experimental test of 533 00:22:27,350 --> 00:22:24,720 this design 534 00:22:30,149 --> 00:22:27,360 in order to to be sure 535 00:22:31,029 --> 00:22:30,159 that the tcc works as expected we we 536 00:22:33,510 --> 00:22:31,039 need to 537 00:22:35,669 --> 00:22:33,520 to cut every external disturbance like 538 00:22:37,909 --> 00:22:35,679 for instance man-made and 539 00:22:40,950 --> 00:22:37,919 natural electromagnetic fields 540 00:22:42,549 --> 00:22:40,960 natural reactivity and cosmic particles 541 00:22:43,669 --> 00:22:42,559 and so on 542 00:22:45,909 --> 00:22:43,679 and i am 543 00:22:49,350 --> 00:22:45,919 pretty confident that this could be done 544 00:22:50,950 --> 00:22:49,360 with proper proper shielding 545 00:22:53,110 --> 00:22:50,960 you must also avoid 546 00:22:55,190 --> 00:22:53,120 any non-uniformity 547 00:22:57,190 --> 00:22:55,200 of the ambient temperature around the 548 00:22:59,909 --> 00:22:57,200 device and the measuring 549 00:23:02,310 --> 00:22:59,919 instruments in order to prevent 550 00:23:03,669 --> 00:23:02,320 any thermoelectric effect 551 00:23:05,990 --> 00:23:03,679 and 552 00:23:09,909 --> 00:23:06,000 also a prescription 553 00:23:11,430 --> 00:23:09,919 peculiar to this case may be that of uh 554 00:23:14,070 --> 00:23:11,440 placing 555 00:23:15,590 --> 00:23:14,080 side by side two tcc's identical in 556 00:23:17,190 --> 00:23:15,600 every respect 557 00:23:20,310 --> 00:23:17,200 exception made for 558 00:23:22,710 --> 00:23:20,320 the fact that one does not have the the 559 00:23:23,830 --> 00:23:22,720 the lower function coating 560 00:23:26,870 --> 00:23:23,840 you know 561 00:23:28,789 --> 00:23:26,880 that prescription should should allow 562 00:23:30,470 --> 00:23:28,799 discriminating between the the real 563 00:23:32,310 --> 00:23:30,480 contribution 564 00:23:34,070 --> 00:23:32,320 of the terminic emission 565 00:23:36,710 --> 00:23:34,080 and the 566 00:23:37,830 --> 00:23:36,720 the background noise 567 00:23:40,630 --> 00:23:37,840 uh 568 00:23:43,190 --> 00:23:40,640 finally just a few words 569 00:23:45,269 --> 00:23:43,200 on the measuring equipment as we have 570 00:23:46,870 --> 00:23:45,279 seen in the previous slide the the 571 00:23:48,789 --> 00:23:46,880 magnitude 572 00:23:52,710 --> 00:23:48,799 of the resistance in the short circuit 573 00:23:54,310 --> 00:23:52,720 dcc must be very high very high 574 00:23:56,630 --> 00:23:54,320 to have a 575 00:23:58,549 --> 00:23:56,640 measurable volt across the device 576 00:24:00,230 --> 00:23:58,559 and so in order to detect something 577 00:24:01,990 --> 00:24:00,240 different from zero 578 00:24:04,070 --> 00:24:02,000 we will need 579 00:24:07,110 --> 00:24:04,080 an ultra high input impedance 580 00:24:09,430 --> 00:24:07,120 electrometer and uh 581 00:24:13,269 --> 00:24:09,440 i know that on the market is available 582 00:24:15,190 --> 00:24:13,279 with one hitley 65 14 that 583 00:24:17,669 --> 00:24:15,200 has 584 00:24:22,310 --> 00:24:17,679 an ultra high impedance of the order of 585 00:24:26,310 --> 00:24:24,950 okay here you may see some selected 586 00:24:30,470 --> 00:24:26,320 references 587 00:24:31,750 --> 00:24:30,480 to my work on the on the tcc and 588 00:24:36,390 --> 00:24:31,760 i am finished 589 00:24:36,400 --> 00:24:42,470 wonderful thank you germano 590 00:24:47,430 --> 00:24:44,470 okay um 591 00:24:49,430 --> 00:24:47,440 you you ended excuse me you ended quite 592 00:24:50,789 --> 00:24:49,440 early so we have a great deal of time 593 00:24:52,470 --> 00:24:50,799 for questions 594 00:24:54,230 --> 00:24:52,480 um okay 595 00:25:03,190 --> 00:24:54,240 so 596 00:25:05,510 --> 00:25:03,200 would you like to start with questions 597 00:25:08,870 --> 00:25:05,520 uh yes my hand however went up for the 598 00:25:11,190 --> 00:25:08,880 last lecture i said i apologize but i 599 00:25:13,510 --> 00:25:11,200 think i have an important point perhaps 600 00:25:16,070 --> 00:25:13,520 to contribute to the last lecture okay 601 00:25:18,230 --> 00:25:16,080 that would be possible sure 602 00:25:20,630 --> 00:25:18,240 uh when you're talking about kel when 603 00:25:22,870 --> 00:25:20,640 you're talking about kirschkov's laws 604 00:25:24,390 --> 00:25:22,880 you're in this funny domain between the 605 00:25:26,390 --> 00:25:24,400 ee 606 00:25:27,909 --> 00:25:26,400 uh who dropped out of physics because he 607 00:25:29,990 --> 00:25:27,919 couldn't handle the math and the 608 00:25:31,830 --> 00:25:30,000 physicists i'm only being very humorous 609 00:25:33,269 --> 00:25:31,840 about it but at any rate but i am 610 00:25:35,669 --> 00:25:33,279 serious and that when you're at a 611 00:25:38,070 --> 00:25:35,679 circuit kirshkov level 612 00:25:40,390 --> 00:25:38,080 uh all of a sudden a bunch of physics 613 00:25:42,549 --> 00:25:40,400 tends to drop away and it's not 614 00:25:44,870 --> 00:25:42,559 considered and in our work at the 615 00:25:46,310 --> 00:25:44,880 intelligent institute we we love this 616 00:25:48,549 --> 00:25:46,320 capacitor problem i thought the 617 00:25:50,390 --> 00:25:48,559 presentation was incredible and i think 618 00:25:52,710 --> 00:25:50,400 it's going to lead to a lot of important 619 00:25:54,149 --> 00:25:52,720 things at any rate let me get to the 620 00:25:56,230 --> 00:25:54,159 point and that is that when you're doing 621 00:25:57,669 --> 00:25:56,240 kirchhoff's law you've got to realize 622 00:26:00,149 --> 00:25:57,679 you're dealing with it across the 623 00:26:01,990 --> 00:26:00,159 resistor or the or any element 624 00:26:10,789 --> 00:26:02,000 you have a 625 00:26:12,630 --> 00:26:10,799 now we got to remember og electric field 626 00:26:14,230 --> 00:26:12,640 uh we really can't talk about we got to 627 00:26:15,350 --> 00:26:14,240 talk about the electrons right the 628 00:26:17,590 --> 00:26:15,360 electrons and therefore they're 629 00:26:19,269 --> 00:26:17,600 accelerating faster as they go through 630 00:26:21,990 --> 00:26:19,279 the electric field they're not all at 631 00:26:23,350 --> 00:26:22,000 the same speed and some of them can get 632 00:26:24,950 --> 00:26:23,360 quite fast 633 00:26:27,029 --> 00:26:24,960 then of course you've got the flow of 634 00:26:29,350 --> 00:26:27,039 like the newton pendulums hitting one 635 00:26:31,830 --> 00:26:29,360 another that kind of a group velocity 636 00:26:33,990 --> 00:26:31,840 versus the actual phase phase velocity 637 00:26:36,310 --> 00:26:34,000 versus group velocity and then you get a 638 00:26:38,310 --> 00:26:36,320 whole bunch of other electromagnetic 639 00:26:40,230 --> 00:26:38,320 effects and then of course by now you 640 00:26:41,669 --> 00:26:40,240 know i'm a time space guy and so 641 00:26:44,390 --> 00:26:41,679 therefore i'm always thinking out of 642 00:26:47,510 --> 00:26:44,400 photons but of a photon is nothing more 643 00:26:49,269 --> 00:26:47,520 than an accelerated charge uh 644 00:26:51,029 --> 00:26:49,279 communicating to another accelerated 645 00:26:53,029 --> 00:26:51,039 charge so all i'm saying is that i think 646 00:26:55,830 --> 00:26:53,039 if those elements can be brought into 647 00:26:57,750 --> 00:26:55,840 this namely the electric field 648 00:26:59,430 --> 00:26:57,760 the uh whatever you i don't believe in 649 00:27:01,590 --> 00:26:59,440 fields but the electric field the the 650 00:27:03,909 --> 00:27:01,600 but mainly the effect of of accelerated 651 00:27:04,950 --> 00:27:03,919 charges to accelerated charges we might 652 00:27:06,390 --> 00:27:04,960 and of course 653 00:27:08,470 --> 00:27:06,400 all everything you're talking about in 654 00:27:10,870 --> 00:27:08,480 thermal is nothing more than accelerated 655 00:27:12,710 --> 00:27:10,880 charges talking to accelerated charges 656 00:27:15,350 --> 00:27:12,720 if you can start to think at that model 657 00:27:19,190 --> 00:27:15,360 level you're now at a commonality where 658 00:27:21,190 --> 00:27:19,200 this unuseful energy is the same as the 659 00:27:24,230 --> 00:27:21,200 so-called useful energy it just has a 660 00:27:25,830 --> 00:27:24,240 different time space nature to it and 661 00:27:27,830 --> 00:27:25,840 and the way in which these accelerated 662 00:27:29,909 --> 00:27:27,840 charges which we're calling photons 663 00:27:32,389 --> 00:27:29,919 communicate from one charged particle to 664 00:27:35,350 --> 00:27:32,399 another so getting back to it kirschkov 665 00:27:37,669 --> 00:27:35,360 laws involves fields because the voltage 666 00:27:39,269 --> 00:27:37,679 changes it causes therefore a different 667 00:27:40,950 --> 00:27:39,279 speed of the electrons traveling through 668 00:27:43,110 --> 00:27:40,960 these circuits they're not traveling at 669 00:27:44,870 --> 00:27:43,120 the same speed and i would love to see 670 00:27:48,230 --> 00:27:44,880 this consideration brought into this 671 00:27:50,950 --> 00:27:48,240 wonderful work and see what comes out 672 00:27:53,510 --> 00:27:50,960 germano would you like to comment 673 00:27:54,789 --> 00:27:53,520 okay yes thank you for the questions 674 00:27:56,870 --> 00:27:54,799 well 675 00:27:59,669 --> 00:27:56,880 i i i agree with you that 676 00:28:02,210 --> 00:27:59,679 my analysis that you see you may see now 677 00:28:03,430 --> 00:28:02,220 on on the screen is probably um 678 00:28:05,350 --> 00:28:03,440 [Music] 679 00:28:07,590 --> 00:28:05,360 too simple okay 680 00:28:09,909 --> 00:28:07,600 and i agree with you that we we need to 681 00:28:10,789 --> 00:28:09,919 put into the into consideration 682 00:28:13,190 --> 00:28:10,799 other 683 00:28:15,350 --> 00:28:13,200 factors that 684 00:28:17,830 --> 00:28:15,360 may have an effect on 685 00:28:19,110 --> 00:28:17,840 on the final results of the 686 00:28:21,750 --> 00:28:19,120 calculation 687 00:28:24,710 --> 00:28:21,760 and 688 00:28:26,470 --> 00:28:24,720 for this reason i myself i am i am the 689 00:28:29,590 --> 00:28:26,480 first person who 690 00:28:32,230 --> 00:28:29,600 in fact do not believe too much to this 691 00:28:35,510 --> 00:28:32,240 calculation to these results which are 692 00:28:37,990 --> 00:28:35,520 mainly theoretical results okay so 693 00:28:38,950 --> 00:28:38,000 what i want to stress is try 694 00:28:39,830 --> 00:28:38,960 to 695 00:28:41,269 --> 00:28:39,840 in 696 00:28:43,510 --> 00:28:41,279 physical implement and check 697 00:28:44,470 --> 00:28:43,520 experimentally this design in order to 698 00:28:47,190 --> 00:28:44,480 see 699 00:28:49,430 --> 00:28:47,200 taking all the prescription i i say 700 00:28:52,310 --> 00:28:49,440 before in the last in 701 00:28:53,750 --> 00:28:52,320 the penultimate slide in order to 702 00:28:57,029 --> 00:28:53,760 to be sure that 703 00:29:00,950 --> 00:28:57,039 the device work as uh as expected okay 704 00:29:02,710 --> 00:29:00,960 um i agree with the with the robert that 705 00:29:04,389 --> 00:29:02,720 using only uh 706 00:29:05,830 --> 00:29:04,399 the cash of law and 707 00:29:08,070 --> 00:29:05,840 neglecting some 708 00:29:09,190 --> 00:29:08,080 factors that 709 00:29:11,909 --> 00:29:09,200 they can 710 00:29:14,310 --> 00:29:11,919 maybe must be taken into account okay in 711 00:29:16,230 --> 00:29:14,320 the calculation of educational law uh 712 00:29:18,630 --> 00:29:16,240 could change the picture 713 00:29:20,870 --> 00:29:18,640 and this is the reason why i 714 00:29:23,029 --> 00:29:20,880 i just presented this this 715 00:29:26,789 --> 00:29:23,039 simple analysis and 716 00:29:29,350 --> 00:29:26,799 simulation and medical simulation but 717 00:29:31,430 --> 00:29:29,360 my goal my targeting my future target is 718 00:29:34,470 --> 00:29:31,440 to to try to 719 00:29:35,990 --> 00:29:34,480 actually test check experimentally okay 720 00:29:39,029 --> 00:29:36,000 the 721 00:29:44,230 --> 00:29:40,630 thank you thank you very much for your 722 00:29:47,190 --> 00:29:44,240 response but uh this was also primarily 723 00:29:51,830 --> 00:29:47,200 uh to paul uh thibaut and uh if he's 724 00:29:58,470 --> 00:29:52,630 uh 725 00:30:00,549 --> 00:29:58,480 think you know a lot of what we've done 726 00:30:02,630 --> 00:30:00,559 really i think was first done kind of in 727 00:30:03,909 --> 00:30:02,640 the optics community where they really 728 00:30:06,549 --> 00:30:03,919 looked at 729 00:30:08,310 --> 00:30:06,559 uh noise and um 730 00:30:09,909 --> 00:30:08,320 the different effects that that can 731 00:30:11,909 --> 00:30:09,919 happen there and actually sarandra 732 00:30:13,029 --> 00:30:11,919 saying it was part of our group is kind 733 00:30:16,470 --> 00:30:13,039 of a 734 00:30:18,389 --> 00:30:16,480 uh you know skilled in that art and so 735 00:30:20,630 --> 00:30:18,399 um you know i basically i agree with you 736 00:30:22,149 --> 00:30:20,640 and i think that the um 737 00:30:23,269 --> 00:30:22,159 you know i think that that field 738 00:30:26,950 --> 00:30:23,279 probably 739 00:30:29,350 --> 00:30:26,960 uh can get uh to do more fundamental uh 740 00:30:31,510 --> 00:30:29,360 look at these things 741 00:30:32,310 --> 00:30:31,520 thank you 742 00:30:34,470 --> 00:30:32,320 okay 743 00:30:35,430 --> 00:30:34,480 thank you um i'd like to call on david 744 00:30:40,389 --> 00:30:35,440 miller 745 00:30:40,399 --> 00:30:46,789 david are you there 746 00:30:53,669 --> 00:30:48,070 okay 747 00:30:57,110 --> 00:30:53,679 to do then is just uh kind of wait wait 748 00:30:59,669 --> 00:30:57,120 for david to get on i'll i'll exert um 749 00:31:01,909 --> 00:30:59,679 the privilege of the chair um germano i 750 00:31:04,389 --> 00:31:01,919 have a couple of questions um concerning 751 00:31:06,549 --> 00:31:04,399 your your talk first of all um 752 00:31:08,230 --> 00:31:06,559 the steady state voltage that you're 753 00:31:12,070 --> 00:31:08,240 you're claiming it looks like it's 754 00:31:13,430 --> 00:31:12,080 around 30 uh millivolts and that's 755 00:31:15,669 --> 00:31:13,440 roughly the thermal 756 00:31:18,389 --> 00:31:15,679 uh voltage that you'd expect from 757 00:31:19,909 --> 00:31:18,399 setting kt equals to qv is that 758 00:31:22,230 --> 00:31:19,919 coincidence or 759 00:31:25,110 --> 00:31:22,240 is there is that is that is there a 760 00:31:25,120 --> 00:31:28,630 well i i believe that 761 00:31:30,950 --> 00:31:29,830 i don't know if 762 00:31:33,830 --> 00:31:30,960 there is a 763 00:31:35,350 --> 00:31:33,840 if it is a coincidence but 764 00:32:16,950 --> 00:31:35,360 i 765 00:32:19,190 --> 00:32:16,960 okay yeah 766 00:32:20,389 --> 00:32:19,200 yeah we'll just please share that again 767 00:32:22,870 --> 00:32:20,399 because i have a 768 00:32:24,230 --> 00:32:22,880 more fun another fundamental question 769 00:32:26,870 --> 00:32:24,240 okay this one 770 00:32:29,350 --> 00:32:26,880 yeah that's that's good okay so um you 771 00:32:31,590 --> 00:32:29,360 you have a a horseshoe here which looks 772 00:32:34,710 --> 00:32:31,600 very much like upside down version of 773 00:32:37,269 --> 00:32:34,720 horseshoes that i had were using in um 774 00:32:38,470 --> 00:32:37,279 and solid state versions of uh 775 00:32:41,190 --> 00:32:38,480 challenges 776 00:32:44,389 --> 00:32:41,200 and the junction one that you have here 777 00:32:46,630 --> 00:32:44,399 um would be the depletion region yeah 778 00:32:47,669 --> 00:32:46,640 between two semiconductors and the j2 779 00:32:50,870 --> 00:32:47,679 gap 780 00:32:53,110 --> 00:32:50,880 um but um you're correct that the that 781 00:32:55,830 --> 00:32:53,120 when when you first join these junctions 782 00:32:58,230 --> 00:32:55,840 that the in the upper junction j2 you 783 00:33:00,470 --> 00:32:58,240 don't initially immediately get charges 784 00:33:02,310 --> 00:33:00,480 but in the end you have to 785 00:33:04,549 --> 00:33:02,320 um and that's that's demanded by 786 00:33:06,389 --> 00:33:04,559 faraday's law or conservation of energy 787 00:33:08,310 --> 00:33:06,399 kirchhoff's law in other words if you 788 00:33:11,590 --> 00:33:08,320 wish if you take a if you take an 789 00:33:13,990 --> 00:33:11,600 integral around a closed loop 790 00:33:15,590 --> 00:33:14,000 the electric field 791 00:33:17,669 --> 00:33:15,600 net electric field around a closed loop 792 00:33:19,029 --> 00:33:17,679 line integral has to be zero so if you 793 00:33:20,470 --> 00:33:19,039 have an electric field here you have to 794 00:33:22,149 --> 00:33:20,480 have electric field somewhere else in 795 00:33:23,430 --> 00:33:22,159 the system it can't be in the bolt 796 00:33:25,590 --> 00:33:23,440 because that would drive a current 797 00:33:28,789 --> 00:33:25,600 therefore it has to be across the gap 798 00:33:31,110 --> 00:33:28,799 so straight faraday straight maxwell's 799 00:33:32,950 --> 00:33:31,120 equations demands that that in steady 800 00:33:34,149 --> 00:33:32,960 state you have to have charges here on 801 00:33:37,029 --> 00:33:34,159 the gap you have to have an electric 802 00:33:39,110 --> 00:33:37,039 field here but more than that 803 00:33:40,870 --> 00:33:39,120 the electric field has been measured by 804 00:33:43,350 --> 00:33:40,880 multiple groups around the world i've 805 00:33:44,310 --> 00:33:43,360 i've built these these these junction 806 00:33:46,389 --> 00:33:44,320 gaps 807 00:33:47,830 --> 00:33:46,399 in semiconductors and multiple 808 00:33:49,669 --> 00:33:47,840 independent groups have measured the 809 00:33:51,269 --> 00:33:49,679 electric field so in fact there is an 810 00:33:52,470 --> 00:33:51,279 electric field here and that's 811 00:33:54,549 --> 00:33:52,480 experimentally determined and 812 00:33:56,310 --> 00:33:54,559 analytically required if you believe 813 00:33:57,990 --> 00:33:56,320 maxwell's equations 814 00:33:59,590 --> 00:33:58,000 so um i don't know how you want to 815 00:34:01,669 --> 00:33:59,600 respond if you can respond to that i'd 816 00:34:05,029 --> 00:34:01,679 appreciate it well 817 00:34:10,950 --> 00:34:08,550 what i've i have shown here is that 818 00:34:11,750 --> 00:34:10,960 half of the application of a kirchhoff 819 00:34:13,270 --> 00:34:11,760 law 820 00:34:19,190 --> 00:34:13,280 i 821 00:34:21,669 --> 00:34:19,200 shoe 822 00:34:24,629 --> 00:34:21,679 we can extend this 823 00:34:27,030 --> 00:34:24,639 integral to become a circular integral 824 00:34:27,829 --> 00:34:27,040 across the in general okay 825 00:34:30,149 --> 00:34:27,839 and 826 00:34:32,629 --> 00:34:30,159 but i think that what i have shown here 827 00:34:34,790 --> 00:34:32,639 the fact that the 828 00:34:37,829 --> 00:34:34,800 the work done by all the forces acting 829 00:34:39,669 --> 00:34:37,839 upon the text electron across j1 is 830 00:34:42,149 --> 00:34:39,679 still the same also in the in the case 831 00:34:43,589 --> 00:34:42,159 of a circular of um 832 00:34:44,950 --> 00:34:43,599 closer the 833 00:34:45,750 --> 00:34:44,960 integrals okay 834 00:34:48,950 --> 00:34:45,760 and 835 00:34:49,990 --> 00:34:48,960 you should 836 00:34:53,190 --> 00:34:50,000 according 837 00:34:55,669 --> 00:34:53,200 this is my my position okay 838 00:34:58,310 --> 00:34:55,679 should be also equal to zero because you 839 00:35:00,630 --> 00:34:58,320 see it is equal to zero the the the work 840 00:35:03,589 --> 00:35:00,640 the the wall work the overall work done 841 00:35:05,750 --> 00:35:03,599 by all the forces across j1 okay and 842 00:35:06,710 --> 00:35:05,760 because in in the balance of 843 00:35:11,990 --> 00:35:06,720 in 844 00:35:15,270 --> 00:35:12,000 the electric force due to the the built 845 00:35:17,670 --> 00:35:15,280 in electric field across j1 but also 846 00:35:19,510 --> 00:35:17,680 the diffusion forces that must be always 847 00:35:21,990 --> 00:35:19,520 there 848 00:35:23,829 --> 00:35:22,000 must be always present and the forces 849 00:35:25,910 --> 00:35:23,839 the diffusion forces 850 00:35:29,030 --> 00:35:25,920 should be equal and opposite to the the 851 00:35:32,150 --> 00:35:29,040 electric field across j1 because 852 00:35:35,349 --> 00:35:32,160 if one is if one could switch could 853 00:35:37,349 --> 00:35:35,359 switch off the these diffusion forces 854 00:35:40,550 --> 00:35:37,359 the built-in electric field will go to 855 00:35:42,790 --> 00:35:40,560 zero immediately okay yeah 856 00:35:45,750 --> 00:35:42,800 i am i agree with you that 857 00:35:47,510 --> 00:35:45,760 the electric field has been 858 00:35:50,630 --> 00:35:47,520 measured 859 00:35:51,510 --> 00:35:50,640 yeah 860 00:35:53,910 --> 00:35:51,520 i'm 861 00:35:56,630 --> 00:35:53,920 now thinking of of the 862 00:35:59,270 --> 00:35:56,640 the use of the kelvin kelvin probe 863 00:36:01,670 --> 00:35:59,280 system to to to measure the this field 864 00:36:04,150 --> 00:36:01,680 probably right well the kelvin probes 865 00:36:06,230 --> 00:36:04,160 were used to measure yeah that j2 866 00:36:08,470 --> 00:36:06,240 electric field the thing is though is in 867 00:36:11,270 --> 00:36:08,480 terms of the forces in the in the in the 868 00:36:13,589 --> 00:36:11,280 lower gap j1 okay 869 00:36:14,870 --> 00:36:13,599 you have i mean the electric field that 870 00:36:16,470 --> 00:36:14,880 builds up there in the first place is 871 00:36:17,910 --> 00:36:16,480 due to diffusion cross-diffusion of 872 00:36:18,950 --> 00:36:17,920 charges at least in the semiconductor 873 00:36:21,109 --> 00:36:18,960 case 874 00:36:22,550 --> 00:36:21,119 and and in terms of diffusion forces if 875 00:36:23,990 --> 00:36:22,560 you're talking about brownian motion 876 00:36:25,430 --> 00:36:24,000 that that's uh 877 00:36:27,510 --> 00:36:25,440 that average force is zero and you have 878 00:36:29,750 --> 00:36:27,520 to do a time average of it which gives 879 00:36:31,670 --> 00:36:29,760 you zero there so um that needs to be 880 00:36:34,310 --> 00:36:31,680 this this has to be done delicately this 881 00:36:35,510 --> 00:36:34,320 uh this internal force 882 00:36:38,310 --> 00:36:35,520 so i think you'll find the average 883 00:36:39,510 --> 00:36:38,320 diffusive force um is either zero the 884 00:36:41,349 --> 00:36:39,520 way you're if you're if i'm 885 00:36:42,470 --> 00:36:41,359 understanding it correctly or else is 886 00:36:43,910 --> 00:36:42,480 being double counted because the 887 00:36:46,230 --> 00:36:43,920 electric field of the built-in the 888 00:36:50,470 --> 00:36:46,240 built-in electric field is the result of 889 00:36:55,030 --> 00:36:53,109 okay and diffusion force necessarily 890 00:36:56,150 --> 00:36:55,040 transient because you know electrons 891 00:36:57,270 --> 00:36:56,160 move from one side to the other and then 892 00:36:59,430 --> 00:36:57,280 you have a counter potential that 893 00:37:02,310 --> 00:36:59,440 cancels out the initial potential 894 00:37:04,390 --> 00:37:02,320 difference so then at like long times 895 00:37:06,790 --> 00:37:04,400 you'd expect no diffusion force 896 00:37:08,790 --> 00:37:06,800 well yeah i i'm just kind of i'm fuzzy 897 00:37:10,950 --> 00:37:08,800 on what the diffusion force is here the 898 00:37:12,950 --> 00:37:10,960 electric the built-in uh potential at 899 00:37:14,069 --> 00:37:12,960 least when it comes to semiconductors 900 00:37:16,230 --> 00:37:14,079 they're not talking about metals here 901 00:37:18,310 --> 00:37:16,240 but semiconductors is the result of 902 00:37:19,910 --> 00:37:18,320 diffusion in the first place right 903 00:37:21,349 --> 00:37:19,920 you're you're trading electrostatic 904 00:37:23,109 --> 00:37:21,359 you're trading chemical potential 905 00:37:24,470 --> 00:37:23,119 difference for electrostatic potential 906 00:37:25,750 --> 00:37:24,480 difference there 907 00:37:27,109 --> 00:37:25,760 so if you're throwing in another 908 00:37:29,430 --> 00:37:27,119 diffusion force that would be a 909 00:37:31,109 --> 00:37:29,440 fluctuating force which has a time 910 00:37:34,069 --> 00:37:31,119 average of zero as you're saying i 911 00:37:36,150 --> 00:37:34,079 believe that that's correct yeah so 912 00:37:37,589 --> 00:37:36,160 anyways it's an interesting proposal and 913 00:37:39,109 --> 00:37:37,599 i think yeah the measurements should be 914 00:37:41,990 --> 00:37:39,119 made yeah 915 00:37:43,990 --> 00:37:42,000 definitely yeah 916 00:37:45,190 --> 00:37:44,000 for the medals yeah 917 00:37:47,030 --> 00:37:45,200 so 918 00:37:48,790 --> 00:37:47,040 other other questions on david are you 919 00:37:51,990 --> 00:37:48,800 back 920 00:37:54,310 --> 00:37:52,000 sorry hands up garrett i think you were 921 00:37:56,870 --> 00:37:54,320 yeah you had your hands up too damn 922 00:37:58,950 --> 00:37:56,880 uh david put his question in the chat 923 00:38:02,230 --> 00:37:58,960 because his mic isn't working 924 00:38:04,710 --> 00:38:02,240 uh he he says can um 925 00:38:08,470 --> 00:38:04,720 jomano please address how much current 926 00:38:10,310 --> 00:38:08,480 would go up with increased temperature 927 00:38:11,270 --> 00:38:10,320 okay thank you okay 928 00:38:12,470 --> 00:38:11,280 okay 929 00:38:16,230 --> 00:38:12,480 well 930 00:38:18,630 --> 00:38:16,240 i have in the simulation i have done uh 931 00:38:20,069 --> 00:38:18,640 i used also i made the calculation also 932 00:38:22,069 --> 00:38:20,079 for uh 933 00:38:23,270 --> 00:38:22,079 three for two factor different 934 00:38:26,510 --> 00:38:23,280 temperature 935 00:38:28,790 --> 00:38:26,520 uh 300 kelvin 20 to 936 00:38:31,270 --> 00:38:28,800 296 kelvin 937 00:38:32,790 --> 00:38:31,280 in order to give an idea an ink of how 938 00:38:35,190 --> 00:38:32,800 his uh 939 00:38:36,950 --> 00:38:35,200 in this case the voltage across the the 940 00:38:41,430 --> 00:38:36,960 open circuit necessity 941 00:38:43,829 --> 00:38:41,440 uh change with temperature and um 942 00:38:44,950 --> 00:38:43,839 well i didn't 943 00:38:47,829 --> 00:38:44,960 i didn't 944 00:38:49,270 --> 00:38:47,839 do they has called the calculation 945 00:38:50,630 --> 00:38:49,280 about the the 946 00:38:53,510 --> 00:38:50,640 current 947 00:38:57,910 --> 00:38:56,150 well i i don't know but 948 00:39:00,470 --> 00:38:57,920 i don't know how the dependence of the 949 00:39:01,990 --> 00:39:00,480 current is with temperature uh i should 950 00:39:05,349 --> 00:39:02,000 may i should 951 00:39:07,990 --> 00:39:05,359 redo the calculation in order to see 952 00:39:09,990 --> 00:39:08,000 how the the current across the the short 953 00:39:11,910 --> 00:39:10,000 circuit cc change with the with the 954 00:39:15,109 --> 00:39:11,920 temperature 955 00:39:18,390 --> 00:39:15,119 but i believe that the 956 00:39:19,829 --> 00:39:18,400 the trend is similar to this factor uh 957 00:39:20,790 --> 00:39:19,839 multiplying the 958 00:39:22,790 --> 00:39:20,800 the 959 00:39:24,310 --> 00:39:22,800 this this equation okay 960 00:39:27,270 --> 00:39:24,320 so it 961 00:39:30,550 --> 00:39:27,280 should scale with the the third power of 962 00:39:33,270 --> 00:39:31,670 okay 963 00:39:34,710 --> 00:39:33,280 good 964 00:39:36,710 --> 00:39:34,720 other questions 965 00:39:37,670 --> 00:39:36,720 garrett did you have a question 966 00:39:40,870 --> 00:39:37,680 yes 967 00:39:43,589 --> 00:39:40,880 um so you talk about power but then you 968 00:39:46,230 --> 00:39:43,599 also mentioned needing to use a very 969 00:39:47,670 --> 00:39:46,240 high impedance volt meter to measure 970 00:39:50,710 --> 00:39:47,680 this and 971 00:39:53,270 --> 00:39:50,720 kelvin probe another example 972 00:39:56,630 --> 00:39:53,280 i like to think of 973 00:39:57,990 --> 00:39:56,640 two types of second law violations the 974 00:40:02,310 --> 00:39:58,000 the 975 00:40:03,829 --> 00:40:02,320 violation 976 00:40:06,630 --> 00:40:03,839 and so 977 00:40:09,109 --> 00:40:06,640 for me a soft violation would be 978 00:40:10,710 --> 00:40:09,119 where you produce a potential difference 979 00:40:11,990 --> 00:40:10,720 but you're not actually getting work out 980 00:40:13,030 --> 00:40:12,000 of it 981 00:40:14,550 --> 00:40:13,040 and 982 00:40:16,390 --> 00:40:14,560 i wonder 983 00:40:20,150 --> 00:40:16,400 is this 984 00:40:22,710 --> 00:40:20,160 perhaps a soft violation in which you're 985 00:40:25,270 --> 00:40:22,720 distorting something but it's not clear 986 00:40:28,309 --> 00:40:25,280 that we could get substantial continuous 987 00:40:32,870 --> 00:40:30,309 okay um 988 00:40:37,430 --> 00:40:32,880 well i mean that 989 00:40:41,670 --> 00:40:39,589 a cd current should flow across the 990 00:40:44,470 --> 00:40:41,680 resistor so 991 00:40:47,190 --> 00:40:44,480 even if it is a tiny power output it 992 00:40:49,670 --> 00:40:47,200 should be a continuous uh 993 00:40:53,270 --> 00:40:49,680 power electrical power output 994 00:40:55,589 --> 00:40:53,280 and what they this is how i see 995 00:40:56,710 --> 00:40:55,599 the behavior of this pcc 996 00:40:58,470 --> 00:40:56,720 uh 997 00:41:00,230 --> 00:40:58,480 these two spheres 998 00:41:02,790 --> 00:41:00,240 subtract uh 999 00:41:06,790 --> 00:41:02,800 thermal energy from the the hermitage 1000 00:41:09,030 --> 00:41:06,800 and transform this thermal energy in a 1001 00:41:12,150 --> 00:41:09,040 current that claw that passed across the 1002 00:41:16,710 --> 00:41:12,160 resistor so i believe that it is uh i i 1003 00:41:19,349 --> 00:41:16,720 think that if this uh design works 1004 00:41:20,390 --> 00:41:19,359 probably it works 1005 00:41:22,470 --> 00:41:20,400 violating 1006 00:41:24,069 --> 00:41:22,480 in a strong way the second law of 1007 00:41:27,750 --> 00:41:24,079 thermodynamic 1008 00:41:30,069 --> 00:41:27,760 this is my my 1009 00:41:32,309 --> 00:41:30,079 my idea 1010 00:41:37,829 --> 00:41:34,790 the problem with this design is as you 1011 00:41:41,030 --> 00:41:37,839 may see is the the the very teeny tiny 1012 00:41:42,470 --> 00:41:41,040 power output that is 1013 00:41:45,750 --> 00:41:42,480 too close to the 1014 00:41:49,430 --> 00:41:45,760 the background noise to be detected and 1015 00:41:51,030 --> 00:41:49,440 in an ambiguously uh 1016 00:41:53,270 --> 00:41:51,040 detected 1017 00:41:54,230 --> 00:41:53,280 it's a it's an interesting issue how 1018 00:41:55,109 --> 00:41:54,240 much 1019 00:41:57,750 --> 00:41:55,119 power 1020 00:42:00,470 --> 00:41:57,760 can really be obtained or if nature is 1021 00:42:02,790 --> 00:42:00,480 is kind of limiting this to these small 1022 00:42:04,790 --> 00:42:02,800 numbers for example even with 1023 00:42:05,589 --> 00:42:04,800 paul thibodeau's earlier calculation 1024 00:42:09,510 --> 00:42:05,599 about 1025 00:42:12,710 --> 00:42:09,520 getting power out from a diode and 1026 00:42:13,670 --> 00:42:12,720 daniel's epicatalysis and so on is there 1027 00:42:16,230 --> 00:42:13,680 some 1028 00:42:17,750 --> 00:42:16,240 limit that nature has to uh 1029 00:42:19,109 --> 00:42:17,760 non-linearity 1030 00:42:21,270 --> 00:42:19,119 it ends up 1031 00:42:24,230 --> 00:42:21,280 saying yeah you can violate this but 1032 00:42:26,870 --> 00:42:24,240 just very soft yeah yeah yeah 1033 00:42:29,109 --> 00:42:26,880 i i guess i i the soft and hard 1034 00:42:30,790 --> 00:42:29,119 violation i think is i 1035 00:42:32,550 --> 00:42:30,800 i'm wondering whether that's somewhat of 1036 00:42:34,710 --> 00:42:32,560 a red herring um 1037 00:42:36,230 --> 00:42:34,720 in in the sense that 1038 00:42:39,750 --> 00:42:36,240 there's more than one way to skin a cat 1039 00:42:41,030 --> 00:42:39,760 i mean if you're if if 1040 00:42:41,910 --> 00:42:41,040 it may look 1041 00:42:44,630 --> 00:42:41,920 more 1042 00:42:46,309 --> 00:42:44,640 in 1043 00:42:48,470 --> 00:42:46,319 and then you probably should consider 1044 00:42:51,030 --> 00:42:48,480 thermal noise then nyquist or johnson 1045 00:42:53,510 --> 00:42:51,040 noise to to compete here but on the 1046 00:42:54,950 --> 00:42:53,520 other hand if you go again back to that 1047 00:42:56,309 --> 00:42:54,960 slide five 1048 00:42:59,430 --> 00:42:56,319 there's more than there are other ways 1049 00:43:02,150 --> 00:42:59,440 of extracting that energy and 1050 00:43:04,710 --> 00:43:02,160 there have been propositions for in the 1051 00:43:05,910 --> 00:43:04,720 semiconductor case of using the gap two 1052 00:43:07,829 --> 00:43:05,920 electric fields to drive 1053 00:43:10,550 --> 00:43:07,839 electromechanical devices 1054 00:43:13,109 --> 00:43:10,560 and and detailed numerical simulations 1055 00:43:15,270 --> 00:43:13,119 indicate that that's feasible 1056 00:43:17,510 --> 00:43:15,280 and so what may look like a soft 1057 00:43:19,829 --> 00:43:17,520 violation in one 1058 00:43:21,430 --> 00:43:19,839 in some light if you cast it in a 1059 00:43:23,750 --> 00:43:21,440 different light a different kind of work 1060 00:43:32,309 --> 00:43:23,760 extraction it becomes the soft violation 1061 00:43:36,870 --> 00:43:34,150 i also think zero is just the most 1062 00:43:39,030 --> 00:43:36,880 fundamental limit on work extraction so 1063 00:43:40,230 --> 00:43:39,040 if you can extract anything it seems 1064 00:43:41,829 --> 00:43:40,240 at this point it's no longer a 1065 00:43:44,950 --> 00:43:41,839 fundamental physics problem it's just a 1066 00:43:46,309 --> 00:43:44,960 matter of engineering you know i think 1067 00:43:47,589 --> 00:43:46,319 history shows that we started with all 1068 00:43:49,510 --> 00:43:47,599 these small effects over and over in 1069 00:43:51,190 --> 00:43:49,520 physics with enough kind of money being 1070 00:43:53,750 --> 00:43:51,200 put on a problem you know we have these 1071 00:43:55,510 --> 00:43:53,760 drastic increases right if you just kind 1072 00:43:56,870 --> 00:43:55,520 of bound this once you get over that 1073 00:43:57,910 --> 00:43:56,880 initial violation 1074 00:44:00,230 --> 00:43:57,920 sure 1075 00:44:02,230 --> 00:44:00,240 yeah like for instance some of the more 1076 00:44:03,750 --> 00:44:02,240 recent epic catalysis 1077 00:44:06,390 --> 00:44:03,760 experiments with 1078 00:44:08,950 --> 00:44:06,400 with david miller here at usd those are 1079 00:44:11,030 --> 00:44:08,960 putting out milliwatts now um that's 1080 00:44:12,870 --> 00:44:11,040 that's not i mean it's not large but 1081 00:44:16,470 --> 00:44:12,880 it's more than picowatts 1082 00:44:17,190 --> 00:44:16,480 and milliwatts are are easily measurable 1083 00:44:19,190 --> 00:44:17,200 so 1084 00:44:25,829 --> 00:44:19,200 it's no longer a quantum fluctuation no 1085 00:44:29,990 --> 00:44:28,230 okay other questions um i'm having a 1086 00:44:31,589 --> 00:44:30,000 hard time seeing everyone's hand here so 1087 00:44:33,510 --> 00:44:31,599 if you have a question please just jump 1088 00:44:34,390 --> 00:44:33,520 in and we'll sort it out 1089 00:44:36,950 --> 00:44:34,400 okay 1090 00:44:38,470 --> 00:44:36,960 i have a question to paul tibaldo 1091 00:44:39,670 --> 00:44:38,480 to raise this 1092 00:44:42,710 --> 00:44:39,680 um 1093 00:44:44,390 --> 00:44:42,720 and and uh my question is two question 1094 00:44:45,430 --> 00:44:44,400 or three questions 1095 00:44:47,349 --> 00:44:45,440 even 1096 00:44:50,150 --> 00:44:47,359 uh 1097 00:44:55,990 --> 00:44:50,160 first question how high is the voltage 1098 00:44:59,109 --> 00:44:57,109 uh 1099 00:44:59,990 --> 00:44:59,119 hey hey 1100 00:45:02,390 --> 00:45:00,000 um 1101 00:45:04,150 --> 00:45:02,400 okay did you want to do this okay hold 1102 00:45:06,630 --> 00:45:04,160 on a second you said time this way 1103 00:45:08,790 --> 00:45:06,640 daniel sorry yeah yeah um so let's let's 1104 00:45:11,030 --> 00:45:08,800 border here hold on hold on a second 1105 00:45:13,750 --> 00:45:11,040 paul are there any are there anything 1106 00:45:15,670 --> 00:45:13,760 are there any questions uh of any 1107 00:45:19,349 --> 00:45:15,680 further questions 1108 00:45:22,550 --> 00:45:19,359 for um germano brumo 1109 00:45:32,550 --> 00:45:23,510 okay 1110 00:45:34,230 --> 00:45:32,560 so 1111 00:45:36,390 --> 00:45:34,240 uh i'm not sure i quite followed the 1112 00:45:38,630 --> 00:45:36,400 question so the so the so the graphing 1113 00:45:41,270 --> 00:45:38,640 the small capacitor 1114 00:45:44,790 --> 00:45:41,280 uh has an average voltage of zero but it 1115 00:45:46,790 --> 00:45:44,800 does have large voltage fluctuations 1116 00:45:47,990 --> 00:45:46,800 and if you make that capacitance smaller 1117 00:45:50,550 --> 00:45:48,000 and smaller then the voltage 1118 00:45:53,430 --> 00:45:50,560 fluctuations rise this is kind of a 1119 00:45:56,069 --> 00:45:53,440 well-known phenomenon in fact you see it 1120 00:45:57,829 --> 00:45:56,079 in the semiconductor industry if you 1121 00:45:59,990 --> 00:45:57,839 make these chips 1122 00:46:02,870 --> 00:46:00,000 and you make really small capacitors on 1123 00:46:04,790 --> 00:46:02,880 these chips you have to be aware of the 1124 00:46:07,270 --> 00:46:04,800 the large voltage noise that gets 1125 00:46:09,510 --> 00:46:07,280 generated by them 1126 00:46:11,710 --> 00:46:09,520 so i mean the extra energy in this 1127 00:46:15,910 --> 00:46:11,720 circuit comes from the 1128 00:46:17,829 --> 00:46:15,920 fluctuations of of the graphene 1129 00:46:18,790 --> 00:46:17,839 layer isn't it 1130 00:46:20,069 --> 00:46:18,800 okay 1131 00:46:21,990 --> 00:46:20,079 yes 1132 00:46:23,589 --> 00:46:22,000 because as i looked at this at your 1133 00:46:26,069 --> 00:46:23,599 presentation 1134 00:46:26,870 --> 00:46:26,079 at the very beginning you were you told 1135 00:46:28,080 --> 00:46:26,880 that 1136 00:46:31,190 --> 00:46:28,090 the um 1137 00:46:34,069 --> 00:46:31,200 [Music] 1138 00:46:36,950 --> 00:46:34,079 that the fluctuations of the graphene 1139 00:46:41,510 --> 00:46:36,960 would change the capacity 1140 00:46:43,109 --> 00:46:41,520 of the capacitor so that the um so that 1141 00:46:46,069 --> 00:46:43,119 the um 1142 00:46:46,870 --> 00:46:46,079 the electrons would be drawn from the 1143 00:46:50,230 --> 00:46:46,880 um 1144 00:46:52,630 --> 00:46:50,240 from this battery in one or another 1145 00:46:55,510 --> 00:46:52,640 direction depending on 1146 00:46:56,950 --> 00:46:55,520 um yeah the direction right 1147 00:46:59,030 --> 00:46:56,960 and um 1148 00:47:01,829 --> 00:46:59,040 actually 1149 00:47:03,990 --> 00:47:01,839 this would be drawing the um electron 1150 00:47:07,750 --> 00:47:04,000 from the battery and 1151 00:47:09,670 --> 00:47:07,760 uh transporting it to the capacitor 1152 00:47:11,190 --> 00:47:09,680 all right okay yeah great okay i i'm 1153 00:47:13,190 --> 00:47:11,200 with you now so that's more in the 1154 00:47:15,109 --> 00:47:13,200 deterministic case 1155 00:47:18,230 --> 00:47:15,119 we've done an extremely detailed 1156 00:47:19,109 --> 00:47:18,240 analysis of the deterministic case 1157 00:47:21,589 --> 00:47:19,119 and 1158 00:47:24,470 --> 00:47:21,599 that battery if you if you imagine 1159 00:47:26,549 --> 00:47:24,480 replacing that battery with a capacitor 1160 00:47:28,870 --> 00:47:26,559 it's easier to visualize 1161 00:47:30,549 --> 00:47:28,880 then a little bit of charge comes off on 1162 00:47:32,470 --> 00:47:30,559 the forward direction 1163 00:47:34,710 --> 00:47:32,480 and then a little bit of charge goes 1164 00:47:37,190 --> 00:47:34,720 back onto the capacitor in the reverse 1165 00:47:40,069 --> 00:47:37,200 direction and if it's a loss list if 1166 00:47:43,030 --> 00:47:40,079 it's a very low loss system then you 1167 00:47:45,349 --> 00:47:43,040 won't lose any of that charge over time 1168 00:47:47,670 --> 00:47:45,359 and so and in a detailed analysis and 1169 00:47:48,549 --> 00:47:47,680 this includes not only from physics but 1170 00:47:50,950 --> 00:47:48,559 from 1171 00:47:53,510 --> 00:47:50,960 uh kind of the state-of-the-art in 1172 00:47:54,950 --> 00:47:53,520 in engineering um 1173 00:47:57,270 --> 00:47:54,960 circuit analysis 1174 00:47:59,589 --> 00:47:57,280 that battery contributes none of the 1175 00:48:02,549 --> 00:47:59,599 power in fact it's whatever is turning 1176 00:48:04,390 --> 00:48:02,559 the capacitor if you think of a windmill 1177 00:48:06,390 --> 00:48:04,400 it's whatever is turning the windmill 1178 00:48:07,589 --> 00:48:06,400 that's the origin of power 1179 00:48:08,549 --> 00:48:07,599 it's not 1180 00:48:10,870 --> 00:48:08,559 the 1181 00:48:13,510 --> 00:48:10,880 that's 1182 00:48:15,190 --> 00:48:13,520 present in the system or the or in that 1183 00:48:16,630 --> 00:48:15,200 case maybe a magnetic field that's 1184 00:48:17,670 --> 00:48:16,640 present in a system the power isn't 1185 00:48:19,270 --> 00:48:17,680 coming from that it's coming from 1186 00:48:20,390 --> 00:48:19,280 whatever is turning 1187 00:48:23,030 --> 00:48:20,400 that 1188 00:48:23,990 --> 00:48:23,040 windmill or in this case the capacitor 1189 00:48:26,309 --> 00:48:24,000 okay 1190 00:48:29,910 --> 00:48:26,319 but you need if this battery is 1191 00:48:32,069 --> 00:48:29,920 accumulator and not a common normal 1192 00:48:34,549 --> 00:48:32,079 normal battery 1193 00:48:37,589 --> 00:48:34,559 and you want to 1194 00:48:39,829 --> 00:48:37,599 use this um charge you need an initial 1195 00:48:42,309 --> 00:48:39,839 charge in this accumulator 1196 00:48:45,430 --> 00:48:42,319 to um to 1197 00:48:47,990 --> 00:48:45,440 to make it move you through the 1198 00:48:50,950 --> 00:48:48,000 vibration of 1199 00:48:51,829 --> 00:48:50,960 of the um of the layer of the graphene 1200 00:48:52,790 --> 00:48:51,839 layer 1201 00:48:55,270 --> 00:48:52,800 isn't it 1202 00:48:57,990 --> 00:48:55,280 i'm looking at it as a as an electronic 1203 00:48:59,750 --> 00:48:58,000 engineer as a circuit this is circuit 1204 00:49:03,870 --> 00:48:59,760 and you have a 1205 00:49:08,230 --> 00:49:03,880 battery the battery if it is more than 1206 00:49:10,950 --> 00:49:08,240 0.7 voltage so it at the at the first 1207 00:49:14,549 --> 00:49:10,960 moment when you switch the circuit 1208 00:49:19,349 --> 00:49:14,559 the electron comes and charging through 1209 00:49:23,829 --> 00:49:19,359 the diode d1 the capacitor c1 1210 00:49:30,069 --> 00:49:26,870 what what really happens is um it the 1211 00:49:31,829 --> 00:49:30,079 battery charges the graphing capacitor 1212 00:49:34,069 --> 00:49:31,839 up to the voltage and it's a small 1213 00:49:36,309 --> 00:49:34,079 capacitor so it takes almost no charge 1214 00:49:37,270 --> 00:49:36,319 to do that and then the voltage is zero 1215 00:49:41,030 --> 00:49:37,280 now 1216 00:49:43,589 --> 00:49:41,040 so almost nothing goes into c1 1217 00:49:46,230 --> 00:49:43,599 now as you rotate it there's an ac 1218 00:49:47,670 --> 00:49:46,240 current that's on top of this 1219 00:49:50,309 --> 00:49:47,680 voltage that's sitting there on the 1220 00:49:51,589 --> 00:49:50,319 graphene this is the ac current which is 1221 00:49:54,470 --> 00:49:51,599 charging it 1222 00:49:57,670 --> 00:49:54,480 okay so this capacitor 1223 00:49:59,990 --> 00:49:57,680 c0 is graphing is very small you mean 1224 00:50:02,470 --> 00:50:00,000 okay well yes yes exactly 1225 00:50:04,150 --> 00:50:02,480 okay okay let's wrap it good i'd like to 1226 00:50:07,190 --> 00:50:04,160 redirect back to 1227 00:50:10,309 --> 00:50:07,200 um germano germano are you still here 1228 00:50:12,470 --> 00:50:10,319 okay thank you yeah um yeah yeah so 1229 00:50:14,230 --> 00:50:12,480 germano i'd like to address another 1230 00:50:15,990 --> 00:50:14,240 question if i may just to redirect 1231 00:50:17,829 --> 00:50:16,000 things to this talk um have you 1232 00:50:19,349 --> 00:50:17,839 considered the situation when you have a 1233 00:50:21,430 --> 00:50:19,359 plasma present 1234 00:50:25,190 --> 00:50:21,440 um which can release space charge 1235 00:50:29,190 --> 00:50:26,470 well uh 1236 00:50:31,109 --> 00:50:29,200 actually no i didn't consider 1237 00:50:33,510 --> 00:50:31,119 the presence of plasma 1238 00:50:36,230 --> 00:50:33,520 okay in my design 1239 00:50:39,670 --> 00:50:36,240 uh you are uh alluding to the space 1240 00:50:41,349 --> 00:50:39,680 charge uh between the plates yeah 1241 00:50:43,109 --> 00:50:41,359 yeah 1242 00:50:45,270 --> 00:50:43,119 okay no i did i didn't take into account 1243 00:50:47,670 --> 00:50:45,280 this part but i i 1244 00:50:49,510 --> 00:50:47,680 i know that this should be probably 1245 00:50:52,309 --> 00:50:49,520 included in the in the numerical 1246 00:50:55,030 --> 00:50:52,319 simulation because the 1247 00:50:56,710 --> 00:50:55,040 the presence of the space space charge 1248 00:51:02,390 --> 00:50:56,720 um 1249 00:51:04,790 --> 00:51:02,400 of an open circuit dcc uh 1250 00:51:07,510 --> 00:51:04,800 but i have not included this the 1251 00:51:09,030 --> 00:51:07,520 presence of these charges 1252 00:51:11,670 --> 00:51:09,040 between the players in the in the 1253 00:51:13,109 --> 00:51:11,680 equation in the charging equation 1254 00:51:15,510 --> 00:51:13,119 okay 1255 00:51:16,470 --> 00:51:15,520 and um in terms of power densities do 1256 00:51:18,549 --> 00:51:16,480 you have 1257 00:51:20,069 --> 00:51:18,559 any any estimates or 1258 00:51:21,990 --> 00:51:20,079 feeling for what kind of power densities 1259 00:51:23,829 --> 00:51:22,000 you could achieve if you had small 1260 00:51:25,349 --> 00:51:23,839 enough devices the ones you're proposing 1261 00:51:27,670 --> 00:51:25,359 may be fairly large but if you can 1262 00:51:28,220 --> 00:51:27,680 miniaturize them 1263 00:51:29,670 --> 00:51:28,230 well 1264 00:51:31,910 --> 00:51:29,680 [Music] 1265 00:51:34,230 --> 00:51:31,920 let me share again my 1266 00:51:35,430 --> 00:51:34,240 my presentation because i want to show 1267 00:51:38,470 --> 00:51:35,440 you 1268 00:51:39,510 --> 00:51:38,480 well the the last graph 1269 00:51:41,109 --> 00:51:39,520 this one 1270 00:51:42,630 --> 00:51:41,119 is actually 1271 00:51:45,589 --> 00:51:42,640 the the 1272 00:51:47,990 --> 00:51:45,599 sort of specific or power 1273 00:51:50,710 --> 00:51:48,000 watts per square centimeter 1274 00:51:53,030 --> 00:51:50,720 that can be obtained with the 1275 00:51:56,069 --> 00:51:53,040 with the previous with design 1276 00:51:59,030 --> 00:51:56,079 that i have shown in my presentation and 1277 00:52:00,710 --> 00:51:59,040 also with the the equations 1278 00:52:03,030 --> 00:52:00,720 not taking into account 1279 00:52:04,950 --> 00:52:03,040 all the things we have just all the 1280 00:52:05,829 --> 00:52:04,960 suggestions 1281 00:52:07,990 --> 00:52:05,839 you 1282 00:52:09,510 --> 00:52:08,000 gave me but 1283 00:52:12,950 --> 00:52:09,520 i i 1284 00:52:15,190 --> 00:52:12,960 do not have much hope to have 1285 00:52:17,990 --> 00:52:15,200 power i power with many small devices 1286 00:52:20,069 --> 00:52:18,000 because as you may see the specific or 1287 00:52:22,230 --> 00:52:20,079 the power density of the 1288 00:52:23,910 --> 00:52:22,240 for this specific design is of the order 1289 00:52:25,750 --> 00:52:23,920 10 to the minus 1290 00:52:27,829 --> 00:52:25,760 17 so 1291 00:52:30,950 --> 00:52:27,839 in order to have a microscopic 1292 00:52:34,150 --> 00:52:30,960 production power we we should need not a 1293 00:52:36,470 --> 00:52:34,160 huge tcc but 1294 00:52:37,990 --> 00:52:36,480 moderately small pcc 1295 00:52:39,190 --> 00:52:38,000 connected together 1296 00:52:41,510 --> 00:52:39,200 um 1297 00:52:42,390 --> 00:52:41,520 in series or 1298 00:52:45,190 --> 00:52:42,400 one 1299 00:52:52,230 --> 00:52:48,630 i think that this design cannot be 1300 00:52:54,230 --> 00:52:52,240 mean naturalized okay okay 1301 00:52:57,270 --> 00:52:54,240 right affordable country 1302 00:53:00,549 --> 00:52:57,280 okay well thank you um are there other 1303 00:53:06,309 --> 00:53:02,390 okay well we're coming to the end of the 1304 00:53:08,390 --> 00:53:06,319 the hour and i believe lunch uh is next 1305 00:53:10,230 --> 00:53:08,400 is that right uh gareth 1306 00:53:13,430 --> 00:53:10,240 okay so i think we'll have maybe a few 1307 00:53:15,910 --> 00:53:13,440 minute jump on on that but let's let's 1308 00:53:18,630 --> 00:53:15,920 uh thank uh dr dabramo again thank you 1309 00:53:20,549 --> 00:53:18,640 for uh for a stimulating talk thanks